Electrochemical Synthesis of Poly(3,4-ethylenedioxythiophene) Nanotube Arrays Using ZnO Templates

被引：51

作者：

Doebbelin, M. ^{[1
]}

Tena-Zaera, R. ^{[1
]}

Carrasco, P. M. ^{[1
]}

Sarasua, J. -R. ^{[2
]}

Cabanero, G. ^{[1
]}

Mecerreyes, D. ^{[1
]}

机构：

[1] CIDETEC, New Mat Dept, Ctr Electrochem Technol, Donostia San Sebastian 20009, Spain

[2] Univ Basque Country, Sch Engn, UPV EHU, Bilbao 48013, Spain

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2010年 / 48卷 / 21期

关键词：

conducting polymers; electrochemistry; electropolymerization; nanotechnology; nanotube arrays; PEDOT; polythiophenes; ZnO template; CONDUCTING-POLYMER NANOTUBES; PEDOT; POLYANILINE; SURFACTANT; MECHANISM;

D O I：

10.1002/pola.24251

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new method toward vertically oriented poly(3,4-ethylenedioxythiophene) (PEDOT) nanotube arrays on transparent conductive oxide substrates is presented. The approach is based on the use of ZnO nanowire arrays as templates for the electropolymerization of PEDOT. Robust arrays of vertically oriented PEDOT nanotubes with different lengths and wall thicknesses were obtained by modifying the ZnO nanowire length and charge density passed during the electropolymerization, respectively. Furthermore, PEDOT nanotubes with different morphologies (top-closed and mushroom-like) were successfully designed by varying the PEDOT electropolymerization kinetics or monomer diffusion or both. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 4648-4653, 2010

引用

页码：4648 / 4653

页数：6

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