Synthesis and testing of new end-functionalized oligomers for molecular electronics

被引:52
作者
Flatt, AK
Dirk, SM
Henderson, JC
Shen, DE
Su, J
Reed, MA
Tour, JM
机构
[1] Rice Univ, Dept Chem, Houston, TX 77005 USA
[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA
[3] Yale Univ, Dept Elect Engn, New Haven, CT 06520 USA
[4] Yale Univ, Dept Appl Phys, New Haven, CT 06520 USA
[5] Yale Univ, Dept Phys, New Haven, CT 06520 USA
基金
美国国家科学基金会;
关键词
oligomers; molecular electronics;
D O I
10.1016/j.tet.2003.09.004
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Several new classes of oligomers have been synthesized with functionalities designed to aid in the understanding of molecular device behavior, specifically when molecules are interfaced between proximal electronic probes. The compounds synthesized are series of azobenzenes, bipyridines and oligo(phenylene vinylene)s that bear acetyl-protected thiols for ultimate attachment to metallic surfaces. Some initial electrochemical and solid-state test results are also reported. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8555 / 8570
页数:16
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