Electrochemical capacitive properties of cadmium oxide films

被引:38
作者
Chang, Jinho
Mane, Rajaram S.
Ham, Dukho
Lee, Wonjoo
Cho, Byng Won
Lee, Joong Ki
Han, Sung-Hwan
机构
[1] Hanyang Univ, Dept Chem, Inorgan Nano Mat Lab, Seoul 133791, South Korea
[2] Chonbuk Natl Univ, Res Ctr Ind Technol, Div Environm & Chem Engn, Jeonju 561756, South Korea
关键词
cadmium oxide; surface morphology; XPS; electrodeposition; electrochemical capacitors;
D O I
10.1016/j.electacta.2007.07.056
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The specific capacitances (SC) of cadmium oxide (CdO) films synthesized electrochemically followed by air annealing at 673 K for 2 It onto tin-doped indium oxide (ITO) substrates, in different electrolytes, are estimated using cyclic voltammetry (CV) and galvanostatic discharge experiments and characterized for the structural and surface morphological studies using X-ray diffraction and scanning electron microscopy techniques, respectively. The flake-like surface morphology of CdO film has showed superior SC in KOH electrolyte than that of KNO3, Na2SO4 and NaOH, respectively. Effect of air annealing on shape and enclosed area of CV curves is also studied. Over 1000 cycles, the film electrode was considerably stable, confirming the potentiality of CdO as a capacitive material. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:695 / 699
页数:5
相关论文
共 31 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   QUANTUM EFFICIENCY AND OPTICAL-TRANSITIONS OF CDO PHOTOANODES [J].
BENKO, FA ;
KOFFYBERG, FP .
SOLID STATE COMMUNICATIONS, 1986, 57 (12) :901-903
[3]   Structural, optical and electrical properties of chemically sprayed CdO thin films [J].
Bhosale, CH ;
Kambale, AV ;
Kokate, AV ;
Rajpure, KY .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 122 (01) :67-71
[4]   Electrochemical capacitance in manganese thin films with chevron microstructure [J].
Broughton, JN ;
Brett, MJ .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (12) :A279-A282
[5]   Oxidative synthesis of RuOx•nH2O with ideal capacitive characteristics for supercapacitors [J].
Chang, KH ;
Hu, CC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (07) :A958-A964
[6]   Surface properties of indium-doped Cd2SnO4 ceramics studied by EELS and photoemission spectroscopy [J].
Dou, Y ;
Egdell, RG .
SURFACE SCIENCE, 1997, 372 (1-3) :289-299
[7]   N-type doping in CdO ceramics: a study by EELS and photoemission spectroscopy [J].
Dou, Y ;
Egdell, RG ;
Walker, T ;
Law, DSL ;
Beamson, G .
SURFACE SCIENCE, 1998, 398 (1-2) :241-258
[8]   Carbon nanotube thin films with ordered structures [J].
Du, CS ;
Yeh, J ;
Pan, N .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (05) :548-550
[9]   Electrosynthesis of Bi2O3 thin films and their use in electrochemical supercapacitors [J].
Gujar, T. P. ;
Shinde, V. R. ;
Lokhande, C. D. ;
Han, Sung-Hwan .
JOURNAL OF POWER SOURCES, 2006, 161 (02) :1479-1485
[10]   Synthesis and characterization of liquid MOCVD precursors for thin films of cadmium oxide [J].
Gulino, A ;
Dapporto, P ;
Rossi, P ;
Fragalà, I .
CHEMISTRY OF MATERIALS, 2002, 14 (12) :4955-4962