Metal-organic framework as a template for porous carbon synthesis

被引:1641
作者
Liu, Bo [1 ,2 ]
Shioyama, Hiroshi [1 ]
Akita, Tomoki [1 ]
Xu, Qiang [1 ,2 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan
[2] Kobe Univ, Grad Sch Engn, Nada Ku, Kobe, Hyogo 6578501, Japan
关键词
D O I
10.1021/ja7106146
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porous carbon was synthesized by heating the precursor FA within the pores of MOF-5. The resultant carbon displayed a high specific surface area (BET, 2872 m(2).g (-1)) and important hydrogen uptake (2.6 wt % at 760 Torr, -196 degrees C) as well as excellent electrochemical properties as an electrode material for electrochemical double-layered capacitor (EDLC).
引用
收藏
页码:5390 / +
页数:3
相关论文
共 34 条
[1]   The preparation of active carbons from coal by chemical and physical activation [J].
Ahmadpour, A ;
Do, DD .
CARBON, 1996, 34 (04) :471-479
[2]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[3]   Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].
Chen, BL ;
Eddaoudi, M ;
Hyde, ST ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2001, 291 (5506) :1021-1023
[4]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[5]   Carbon materials for lithium-ion rechargeable batteries [J].
Flandrois, S ;
Simon, B .
CARBON, 1999, 37 (02) :165-180
[6]   Solarthermal and solar quasi-electrolytic processing and separations: Zinc from zinc oxide as an example [J].
Fletcher, EA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1999, 38 (06) :2275-2282
[7]   Synthesis of ordered nanoporous carbons of tunable mesopore size by templating SBA-15 silica materials [J].
Fuertes, AB .
MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 67 (2-3) :273-281
[8]   Deuterium NMR studies of framework and guest mobility in the metal-organic framework compound MOF-5, Zn4O(O2CC6H4CO2)3 [J].
Gonzalez, J ;
Devi, RN ;
Tunstall, DP ;
Cox, PA ;
Wright, PA .
MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 84 (1-3) :97-104
[9]   Synthesis of nitrogen-containing microporous carbon with a highly ordered structure and effect of nitrogen doping on H2O adsorption [J].
Hou, PX ;
Orikasa, H ;
Yamazaki, T ;
Matsuoka, K ;
Tomita, A ;
Setoyama, N ;
Fukushima, Y ;
Kyotani, T .
CHEMISTRY OF MATERIALS, 2005, 17 (20) :5187-5193
[10]   Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles [J].
Joo, SH ;
Choi, SJ ;
Oh, I ;
Kwak, J ;
Liu, Z ;
Terasaki, O ;
Ryoo, R .
NATURE, 2001, 412 (6843) :169-172