Synthesis of chiral polyaniline films via chemical vapor phase polymerization

被引：20

作者：

Chen, J ^{[1
]}

Winther-Jensen, B

Pornputtkul, Y

West, K

Kane-Maquire, L

Wallace, GG

机构：

[1] Univ Wollongong, Intelligent Polymer Res Inst, ARC, Ctr Nanostruct Electromat, Wollongong, NSW 2522, Australia

[2] Riso Natl Lab, Danish Polymer Ctr, DK-4000 Roskilde, Denmark

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2006年 / 9卷 / 01期

关键词：

D O I：

10.1149/1.2136247

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrically and optically active polyaniline films doped with (1)-(-)-10- camphorsulfonic acid were successfully deposited on nonconductive substrates via chemical vapor phase polymerization. The above polyaniline/ R- camphorsulfonate films were characterized by electrochemical and physical methods, such as cyclic voltammetry (CV), UV- vis spectroscopy, four- point probe conductivity measurement, Raman spectroscopy, circular dichroism spectroscopy, and scanning electron microscopy. The polyaniline films grown by this method not only showed high electrochemical activity, supported by CV and Raman spectrum, but also exhibited optical activity corresponding to the polymer chains as observed by circular dichroism spectra. (c) 2005 The Electrochemical Society.

引用

页码：C9 / C11

页数：3

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