Reactions of trifluoromethylthiocopper with halomethanes

被引：27

作者：

Munavalli, S ^{[1
]}

Rossman, DI ^{[1
]}

Rohrbaugh, DK ^{[1
]}

Ferguson, CP ^{[1
]}

Durst, HD ^{[1
]}

机构：

[1] USA,EDGEWOOD CHEM RES DEV & ENGN CTR,ABERDEEN PROVING GROUND,MD 21010

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 76卷 / 01期

关键词：

trifluoromethylthiocopper; halomethanes; reactions; NMR spectroscopy; mass spectrometry;

D O I：

10.1016/0022-1139(95)03332-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of trifluoromethylthiocopper with halomethanes, namely di- and triiodo-, dibromodichloro-, dibromochlorofluoro-, dibromodifluoro-, bromochlorofluoro-, phenyltrichloro-, bromocyano- and dibromofluoro-methanes, has been investigated in detail. In addition to the expected compounds, the formation of unusual products such as bis(trifluoromethyl) trithiocarbonate, dimethyl(trifluoromethylthio)benzene, bis(trifluoromethylthio) fluoromethane, (trifluoromethylthio) carbonyl fluoride, carbon disulfide, carbon tetrachloride, trifluoromethylthiobenzoate, etc. was observed. In some cases, bis(trifluoromethylthio)mercury has been used instead of trifluoromethylthiocopper. The mechanism of formation of the various products and their mass spectral fragmentation behavior are described.

引用

页码：7 / 13

页数：7

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