A new class of organic-inorganic hybrid materials:: Hydrothermal synthesis and structural characterization of bimetallic organophosphonate oxide phases of the Mo/Cu/O/RPO32- family

被引：152

作者：

Finn, RC ^{[1
]}

Zubieta, J ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 11期

关键词：

D O I：

10.1021/ic0100018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reactions of Cu(SO4). SH2O, MoO2, 1,10-phenanthroline, and the appropriate organodiphosphonate ligand yield organic-inorganic hybrid materials with one- or two-dimensional structures; the presence of cluster building blocks is illustrated by the structure of [{CU(H2O)(2)(o-phen)}{Cu(o-phen)(2)}(Mo5O15)(O3PCH2CH2CH2PO3)]. [GRAPHICS]

引用

页码：2466 / +

页数：3

共 9 条

[1]

ALBERTI G, 1996, COMPREHENSIVE SUPRAM, V9, P152

[2] Investigations into the syntheses and structures of clusters of the Mo-O-REO(3)(2-) systems (E=P and As) [J].