Syntheses and UV/Vis properties of amino-functionalized fulgimides

被引：26

作者：

Otto, B ^{[1
]}

Rück-Braun, K ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, Fak 2, D-10623 Berlin, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 13期

关键词：

fulgides; fulgimides; photochromism; UV/Vis spectroscopy; PHOTOCHROMIC HETEROCYCLIC FULGIDES; QUANTUM YIELDS; ANHYDRIDE; DERIVATIVES; SYSTEMS; INDOLYLFULGIDES; FURYLFULGIDES; SUBSTITUENTS; ISOMERS; MOIETY;

D O I：

10.1002/ejoc.200200680

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Functionalized fulgimides are regarded as a promising class of photochromic compounds for modulating the structure and function of biomolecules. A new synthetic route to fulgimides bearing amino-functionalized substituents at the imide nitrogen atom has been developed. The synthesis of the fulgimides has been achieved by base-catalyzed cyclization of phenacyl esters of the succinamic acids derived from fulgides and N-Boc-protected alkyl- and aryl-substituted diamines with triethylamine or tert-butyllithium. The UV/Vis spectroscopic data and the photochromic properties of these new compounds have been studied. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：2409 / 2417

页数：9

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