Rhodium- and iridium-trispyrazolylborate complexes -: C-H activation and coordination chemistry

被引：138

作者：

Slugovc, C

Padilla-Martínez, I

Sirol, S

Carmona, E

机构：

[1] Tech Univ Vienna, Inst Inorgan Chem, A-1060 Vienna, Austria

[2] Univ Sevilla, CSIC, Inst Invest Quim, Dept Quim Inorgan, Seville 41092, Spain

[3] IPN, Unidad Prof Interdisciplinaria Biotecnol, Mexico City 07340, DF, Mexico

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 213卷

关键词：

rhodium; iridium; hydrotris(pyrazolyl)borate; coordination chemistry; C-H activation;

D O I：

10.1016/S0010-8545(00)00365-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review deals with rhodium and iridium complexes of the hydridotris(pyrazolyl)borate (Tp') ligands. In addition to outlining the synthesis of precursor compounds, an overview of the coordination modes of the Tp' ligands is given. Recent developments in the chemistry of some important families of compounds (carbonyls, isonitriles, classical and non-classical polyhydrides) are discussed. Particular attention is given to C-H activation reactions with these compounds. Over 100 references are covered, of which approximately half stem from the last 3 years. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：129 / 157

页数：29

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