Facile synthesis of germanium-graphene nanocomposites and their application as anode materials for lithium ion batteries

被引:92
作者
Cheng, Jinsheng [1 ,2 ]
Du, Jin [1 ]
机构
[1] Guilin Med Univ, Sch Pharm, Guilin 541004, Peoples R China
[2] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
来源
CRYSTENGCOMM | 2012年 / 14卷 / 02期
关键词
HIGH-CAPACITY; CARBON; COMPOSITE; STORAGE; GROWTH;
D O I
10.1039/c1ce06251d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple and low-cost method to synthesize Ge nanoparticles/graphene (Ge NPs/GR) nanocomposites under mild conditions was developed. The reduction of sugarcane bagasse (SB) derived graphene oxide nanosheets was accompanied by generation of Ge NPs in one step. The resulting nanocomposites exhibit high specific capacity and superior capacity retention of 90% after 15 cycles.
引用
收藏
页码:397 / 400
页数:4
相关论文
共 29 条
[11]   Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells [J].
Kasavajjula, Uday ;
Wang, Chunsheng ;
Appleby, A. John .
JOURNAL OF POWER SOURCES, 2007, 163 (02) :1003-1039
[12]   Nanocomposite of Amorphous Ge and Sn Nanoparticles as an Anode Material for Li Secondary Battery [J].
Kim, Min Gyu ;
Cho, Jaephil .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (04) :A277-A282
[13]   Sn78Ge22@carbon core-shell nanowires as fast and high-capacity lithium storage media [J].
Lee, Hyojin ;
Cho, Jaephil .
NANO LETTERS, 2007, 7 (09) :2638-2641
[14]   Synthesis and optimization of nanoparticle Ge confined in a carbon matrix for lithium battery anode material [J].
Lee, Hyojin ;
Kim, Hansu ;
Doo, Seok-Gwang ;
Cho, Jaephil .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (04) :A343-A346
[15]   Silicon nanoparticles-graphene paper composites for Li ion battery anodes [J].
Lee, Jeong K. ;
Smith, Kurt B. ;
Hayner, Cary M. ;
Kung, Harold H. .
CHEMICAL COMMUNICATIONS, 2010, 46 (12) :2025-2027
[16]   Research on Advanced Materials for Li-ion Batteries [J].
Li, Hong ;
Wang, Zhaoxiang ;
Chen, Liquan ;
Huang, Xuejie .
ADVANCED MATERIALS, 2009, 21 (45) :4593-4607
[17]   Pulsed laser deposition and electrochemical characterization of LiFePO4-Ag composite thin films [J].
Lu, Zhouguang ;
Cheng, Hua ;
Lo, Mingfei ;
Chung, C. Y. .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (18) :3885-3896
[18]   Highly reversible lithium storage in spheroidal carbon-coated silicon nanocomposites as anodes for lithium-ion batteries [J].
Ng, See-How ;
Wang, Jiazhao ;
Wexler, David ;
Konstantinov, Konstantin ;
Guo, Zai-Ping ;
Liu, Hua-Kun .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (41) :6896-6899
[19]   Li-alloy based anode materials for Li secondary batteries [J].
Park, Cheol-Min ;
Kim, Jae-Hun ;
Kim, Hansu ;
Sohn, Hun-Joon .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) :3115-3141
[20]   Flexible Dimensional Control of High-Capacity Li-Ion-Battery Anodes: From 0D Hollow to 3D Porous Germanium Nanoparticle Assemblies [J].
Park, Mi-Hee ;
Kim, Kitae ;
Kim, Jeyoung ;
Cho, Jaephil .
ADVANCED MATERIALS, 2010, 22 (03) :415-+