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UV-light induced photocatalytic decolorization of Rhodamine 6G molecules over BiOCl from aqueous solution

被引：126
作者：
Gondal, M. A. [1 ,2 ]
Chang, X. F. [2 ,3 ]
Yamani, Z. H. [1 ,2 ]
机构：
[1] King Fahd Univ Petr & Minerals, Dept Phys, Laser Res Grp, Dhahran 31261, Saudi Arabia
[2] King Fahd Univ Petr & Minerals, Ctr Excellence Nanotechnol, Dhahran 31261, Saudi Arabia
[3] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Dept Appl Chem, Nanjing 211100, Peoples R China
来源：
CHEMICAL ENGINEERING JOURNAL | 2010年 / 165卷 / 01期
关键词：
BiOCl; Sorption kinetics; Sorption isotherm; Photocatalytic; Rhodamine; 6G; Pulsed laser; Mulliken electronegativity; PCP-NA; DEGRADATION; DRIVEN; BR; CL; REMOVAL; SEMICONDUCTORS; ADSORPTION; COMPOSITE; KINETICS;
D O I：
10.1016/j.cej.2010.09.025
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The sorption and photocatalytic decolorization (under irradiation of monochromaticitic 355 nm-pulsed-laser) behaviors of Rhodamine 6G (Rh 6G) in presence of BiOCl semiconductor in aqueous solution were studied in this paper The sorption kinetic and isotherm behaviors of Rh 6G over BiOCl catalyst were investigated and discussed through pseudo-second-order/intraparticle diffusion models and Langmuir/Freundlich models respectively The effect of critical parameters such as catalyst dosage initial concentration of Rh 6G and laser pulse energy on the photocatalytic decolorization process was investigated The photocatalytic decolorization and photonic efficiency of BiOCl was compared with standard catalyst (TiO2) and the obtained results were discussed in terms of their band edge position Finally the chemical stability of BiOCl photocatalyst was studied by measuring the X-ray diffraction (XRD) pattern of BiOCl samples after the reaction (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码：250 / 257
页数：8
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[1]   Efficient Photocatalytic Removal of NO in Indoor Air with Hierarchical Bismuth Oxybromide Nanoplate Microspheres under Visible Light [J].
Ai, Zhihui ;
Ho, Wingkei ;
Lee, Shuncheng ;
Zhang, Lizhi .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (11) :4143-4150
[2]   Photocatalytic properties of BiOX (X = Cl, Br, and I) [J].
An Huizhong ;
Du Yi ;
Wang Tianmin ;
Wang Cong ;
Hao Weichang ;
Zhang Junying .
RARE METALS, 2008, 27 (03) :243-250
[3]   CuAlO2TiO2 heterojunction applied to visible light H2 production [J].
Brahimi, R. ;
Bessekhouad, Y. ;
Bouguelia, A. ;
Trari, M. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 186 (2-3) :242-247
[4]   Heterojunctioned BiOCl/Bi2O3, a new visible light photocatalyst [J].
Chai, Seung Yong ;
Kim, Yong Joo ;
Jung, Myong Hak ;
Chakraborty, Ashok Kumar ;
Jung, Dongwoon ;
Lee, Wan In .
JOURNAL OF CATALYSIS, 2009, 262 (01) :144-149
[5]   Enhancement of photocatalytic activity over NaBiO3/BiOCl composite prepared by an in situ formation strategy [J].
Chang, Xiaofeng ;
Yu, Gang ;
Huang, Jun ;
Li, Zheng ;
Zhu, Shufeng ;
Yu, Pingfeng ;
Cheng, Cheng ;
Deng, Shubo ;
Ji, Guangbin .
CATALYSIS TODAY, 2010, 153 (3-4) :193-199
[6]   BiOX (X = Cl, Br, I) photocatalysts prepared using NaBiO3 as the Bi source: Characterization and catalytic performance [J].
Chang, Xiaofeng ;
Huang, Jun ;
Cheng, Cheng ;
Sui, Qian ;
Sha, Wei ;
Ji, Guangbin ;
Deng, Shubo ;
Yu, Gang .
CATALYSIS COMMUNICATIONS, 2010, 11 (05) :460-464
[7]   Photocatalytic decomposition of 4-t-octylphenol over NaBiO3 driven by visible light: Catalytic kinetics and corrosion products characterization [J].
Chang, Xiaofeng ;
Huang, Jun ;
Cheng, Cheng ;
Sha, Wei ;
Li, Xue ;
Ji, Guangbin ;
Deng, Shubo ;
Yu, Gang .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 173 (1-3) :765-772
[8]   Photocatalytic degradation of PCP-Na over BiOI nanosheets under simulated sunlight irradiation [J].
Chang, Xiaofeng ;
Huang, Jun ;
Tan, Quanyin ;
Wang, Mo ;
Ji, Guangbin ;
Deng, Shubo ;
Yu, Gang .
CATALYSIS COMMUNICATIONS, 2009, 10 (15) :1957-1961
[9]   Fabrication of nanowire-like cuprous oxide in aqueous solutions of a triblock copolymer [J].
Chang, Xiaofeng ;
Ji, Guangbin ;
Shen, Kai ;
Pan, Lijia ;
Shi, Yi ;
Zheng, Youdou .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 482 (1-2) :240-245
[10]   Rapid photocatalytic degradation of PCP-Na over NaBiO3 driven by visible light irradiation [J].
Chang, Xiaofeng ;
Ji, Guangbin ;
Sui, Qian ;
Huang, Jun ;
Yu, Gang .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 166 (2-3) :728-733
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