Novel aromatic oxy-Cope rearrangement. Participation of a benzene ring and intramolecular potassium-ion detachment by methoxy groups

被引：14

作者：

Seki, K

Tooya, M

Sato, T

Ueno, M

Uyehara, T ^{[1
]}

机构：

[1] Utsunomiya Univ, Fac Engn, Dept Appl Chem, Utsunomiya, Tochigi 3218585, Japan

[2] Tohoku Univ, Fac Sci, Instrumental Anal Ctr Chem, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 47期

关键词：

rearrangements; aromatisation; ethers; ketones;

D O I：

10.1016/S0040-4039(98)01869-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aromatic oxy-Cope rearrangement including a benzene ring took place when 1-methoxy-2-arylbicyclo[2.2.2]oct-5-en-2-exo-ols and 2-(2-methoxyphenyl)-bicyclo[2.2.2]oct-5-en-exo-2-ols were treated with KH in THF. (C) 1998 Elsevier Science Ltd. All rights reserved.

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收藏

页码：8673 / 8676

页数：4

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