Controlling the columnar orientation of C3-symmetric "Superbenzenes" through alternating polar/apolar substitutents

被引：55

作者：

Feng, Xinliang ^{[1
]}

Pisula, Wojciech ^{[1
]}

Zhi, Linjie ^{[1
]}

Takase, Masayoshi ^{[1
]}

Muellen, Klaus ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 09期

关键词：

hexa-peri-hexabenzocoronene; liquid crystals; nanostructures; noncovalent interactions; self-assembly;

D O I：

10.1002/anie.200703967

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Everysecond counts: Enhanced control over the self-organization of discotic compounds has been obtained by introducing alternating arrays of apolar (alkyl) and polar (ester) substitutents on to C3-symmetric hexa-peri-hexabenzocoronenes. The local dipole moments and the nanophase separation between the polar and apolar sites significantly influence the self-assembly in solution and in the solid state (see schematic representation). (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1703 / 1706

页数：4

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