Enantiomeric programming in tripodal transition metal scaffolds

被引：25

作者：

Fletcher, Nicholas C. ^{[1
]}

Martin, Ciaran ^{[1
]}

Abraham, Heather J. ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland

来源：

NEW JOURNAL OF CHEMISTRY | 2007年 / 31卷 / 08期

关键词：

D O I：

10.1039/b703761a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new route to the isolation of the enantiopure tris- chelate complex (Delta/Lambda)- fac-[Ru( L-1)(3)] 21 (where L-1 is 2,2'-bipyridine-5-carboxylic acid) is demonstrated, where the transition metal centre retains the memory of the chirality present in a simple tripodal tether used to control the metal centred geometry.

引用

页码：1407 / 1411

页数：5

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