Recent advances in the chemistry of carboranes and metallacarboranes

被引：10

作者：

Hosmane, NS ^{[1
]}

机构：

[1] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

来源：

PURE AND APPLIED CHEMISTRY | 2003年 / 75卷 / 09期

关键词：

D O I：

10.1351/pac200375091219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview of the syntheses, structures, and reactivity of the compounds formed by the incorporation of a number of d- and f-block metals into C2B4- and C2B9-carborane cages have been presented. In addition, the development of a safe, bench-scale preparation of the toxic and commercially unavailable polyhedral borane synthon, namely pentaborane(9), has also been described. Thus, this report discusses the latest deve lopments leading to a systematic synthetic approach to a number of carborane precursors and the subsequent reaction chemistry in the formation of a number of "carbons-apart" metallacarboranes.

引用

页码：1219 / 1229

页数：11

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