A single saddle model for the β-relaxation in supercooled liquids

被引:7
作者
Cavagna, A [1 ]
Giardina, I
Grigera, TS
机构
[1] INFM, Ctr Stat Mech & Complex, Rome, Italy
[2] Ctr Studi & Ric Enrico Fermi, I-00184 Rome, Italy
[3] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
来源
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL | 2003年 / 36卷 / 43期
关键词
D O I
10.1088/0305-4470/36/43/004
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We analyse the relaxational dynamics of a system close to a saddle of the potential energy function, within an harmonic approximation. Our main aim is to relate the topological properties of the saddle, as encoded in its spectrum, to the dynamical behaviour of the system. In the context of the potential energy landscape approach, this represents a first formal step to investigate the belief that the dynamical slowing down at T-c is related to the vanishing of the number of negative modes found at the typical saddle point. In our analysis we keep the description as general as possible, using the spectrum of the saddle as an input. We prove the existence of a timescale t(epsilon), which is uniquely determined by the spectrum, but is not simply related to the fraction of negative eigenvalues. The mean square displacement develops a plateau of length t(epsilon), such that a two-step relaxation is obtained if t(epsilon) diverges at T-c. We analyse different spectral shapes and outline the conditions under which the mean square displacement exhibits a dynamical scaling identical to the beta-relaxation regime of mode coupling theory, with a power-law approach to the plateau and power-law divergence of t(epsilon) at T-c.
引用
收藏
页码:10721 / 10737
页数:17
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