Continuous blade coating for multi-layer large-area organic light-emitting diode and solar cell

被引:50
作者
Chen, Chun-Yu [1 ]
Chang, Hao-Wen [2 ]
Chang, Yu-Fan [3 ]
Chang, Bo-Jie [2 ]
Lin, Yuan-Sheng [3 ]
Jian, Pei-Siou [4 ]
Yeh, Han-Cheng [5 ]
Chien, Hung-Ta [6 ]
Chen, En-Chen [2 ]
Chao, Yu-Chiang [1 ]
Meng, Hsin-Fei [1 ]
Zan, Hsiao-Wen [7 ]
Lin, Hao-Wu [8 ]
Horng, Sheng-Fu [2 ]
Cheng, Yen-Ju [9 ]
Yen, Feng-Wen [10 ]
Lin, I-Feng [10 ]
Yang, Hsiu-Yuan [11 ]
Huang, Kuo-Jui [11 ]
Tseng, Mei-Rurng [12 ]
机构
[1] Natl Chiao Tung Univ, Inst Phys, Hsinchu 300, Taiwan
[2] Natl Tsing Hua Univ, Dept Elect Engn, Hsinchu 300, Taiwan
[3] Natl Tsing Hua Univ, Inst Photon Technol, Hsinchu 300, Taiwan
[4] Natl Chiao Tung Univ, Inst Lighting & Energy Photon, Hsinchu 300, Taiwan
[5] Natl Chiao Tung Univ, Inst Electroopt Engn, Hsinchu 300, Taiwan
[6] Natl Chiao Tung Univ, Dept Electrophys, Hsinchu 300, Taiwan
[7] Natl Chiao Tung Univ, Dept Photon, Hsinchu 300, Taiwan
[8] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 300, Taiwan
[9] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 300, Taiwan
[10] Luminescence Technol Corp, Hsinchu 300, Taiwan
[11] Flash Innovat Co Ltd, Hsinchu 304, Taiwan
[12] Ind Technol Res Inst, Mat & Chem Res Labs, Hsinchu 310, Taiwan
关键词
TRANSPORTING MATERIAL; EFFICIENCY; DEVICES; PERFORMANCE; LAYER;
D O I
10.1063/1.3636398
中图分类号
O59 [应用物理学];
学科分类号
摘要
A continuous roll-to-roll compatible blade-coating method for multi-layers of general organic semiconductors is developed. Dissolution of the underlying film during coating is prevented by simultaneously applying heating from the bottom and gentle hot wind from the top. The solvent is immediately expelled and reflow inhibited. This method succeeds for polymers and small molecules. Uniformity is within 10% for 5 cm by 5 cm area with a mean value of tens of nanometers for both organic light-emitting diode (OLED) and solar cell structure with little material waste. For phosphorescent OLED 25 cd/A is achieved for green, 15 cd/A for orange, and 8 cd/A for blue. For fluorescent OLED 4.3 cd/A is achieved for blue, 9 cd/A for orange, and 6.9 cd/A for white. For OLED with 2 cm by 3 cm active area, the luminance variation is within 10%. Power conversion efficiency of 4.1% is achieved for polymer solar cell, similar to spin coating using the same materials. Very-low-cost and high-throughput fabrication of efficient organic devices is realized by the continuous blade-only method. (C) 2011 American Institute of Physics. [doi:10.1063/1.3636398]
引用
收藏
页数:18
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