Fullerene-based ruthenium catalysts: A novel approach for anchoring metal to carbonaceous supports .2. Hydrogenation activity

被引：35

作者：

Braun, T

Wohlers, M

Belz, T

Schlogl, R

机构：

来源：

CATALYSIS LETTERS | 1997年 / 43卷 / 3-4期

关键词：

carbon support; fullerenes; fullerene black; cathode deposit; ruthenium; hydrogenation; CO; 2-cyclohexenone;

D O I：

10.1023/A:1018950925046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of fullerenes and related support materials on the catalytic properties of ruthenium was investigated The catalytic behaviour of catalysts based on C-60, raw fullerene black, extracted fullerene black, cathode deposit, and graphite was examined using low-temperature CO hydrogenation and liquid-phase hydrogenation of 2-cyclohexenone at atmospheric pressure. The relevance of non-six-membered carbon rings (NSMCR) in support materials on the stability and catalytic performance of the Ru particles will be illustrated.

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页码：175 / 180

页数：6

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