Mono- and dianion of benzoquinone-linked [60]fullerene

被引：31

作者：

Iyoda, M

Sasaki, S

Sultana, F

Yoshida, M

Kuwatani, Y

Nagase, S

机构：

[1] Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 44期

关键词：

D O I：

10.1016/0040-4039(96)01789-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reduction of the benzoquinone-linked [60]fullerene first gives the monoanion containing the semiquinone-radical and C-60 moieties. The further reduction of the monoanion produces the dianion containing the semiquinone-radical and C-60-anion moieties. The EPR spectra of the dianion clearly show the triplet interaction between the semiquinone and C-60 radical anions. Copyright (C) 1996 Elsevier Science Ltd.

引用

收藏

页码：7987 / 7990

页数：4

相关论文

共 27 条

[1] THE UNUSUAL ELECTRON-SPIN-RESONANCE OF FULLERENE C60.- [J].

ALLEMAND, PM ;

SRDANOV, G ;

KOCH, A ;

KHEMANI, K ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) :2780-2781

[2] ORGANIC MOLECULAR SOFT FERROMAGNETISM IN A FULLERENE-C60 [J].

ALLEMAND, PM ;

KHEMANI, KC ;

KOCH, A ;

WUDL, F ;

HOLCZER, K ;

DONOVAN, S ;

GRUNER, G ;

THOMPSON, JD .

SCIENCE, 1991, 253 (5017) :301-303

[3] THE DIELS-ALDER ADDUCT OF C-60 AND 4,5-DIMETHOXY-O-QUINODIMETHANE SYNTHESIS, CRYSTAL-STRUCTURE, AND DONOR-ACCEPTOR BEHAVIOR [J].

BELIK, P ;

GUGEL, A ;

KRAUS, A ;

SPICKERMANN, J ;

ENKELMANN, V ;

FRANK, G ;

MULLEN, K .

ADVANCED MATERIALS, 1993, 5 (11) :854-856

[4] C-60 DERIVATIVE COVALENTLY-LINKED TO A NITROXIDE RADICAL - TIME-RESOLVED EPR EVIDENCE OF ELECTRON-SPIN POLARIZATION BY INTRAMOLECULAR RADICAL-TRIPLET PAIR INTERACTION [J].

CORVAJA, C ;

MAGGINI, M ;

PRATO, M ;

SCORRANO, G ;

VENZIN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (34) :8857-8858

[5] SYNTHESIS OF A FULLERENE DERIVATIVE OF BENZO[18]CROWN-6 BY DIELS-ALDER REACTION - COMPLEXATION ABILITY, AMPHIPHILIC PROPERTIES, AND X-RAY CRYSTAL-STRUCTURE OF A DIMETHOXY-1,9-(METHANO[1,2]BENZENOMETHANO)FULLERENE[60]BENZENE CLATHRATE [J].

DIEDERICH, F ;

JONAS, U ;

GRAMLICH, V ;

HERRMANN, A ;

RINGSDORF, H ;

THILGEN, C .

HELVETICA CHIMICA ACTA, 1993, 76 (07) :2445-2453

[6] ELECTROREDUCTION OF BUCKMINSTERFULLERENE, C-60, IN APROTIC-SOLVENTS - ELECTRON-SPIN-RESONANCE CHARACTERIZATION OF SINGLY, DOUBLY, AND TRIPLY REDUCED C-60 IN FROZEN-SOLUTIONS [J].

DUBOIS, D ;

JONES, MT ;

KADISH, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (16) :6446-6451

[7] ELECTROCHEMICAL EVIDENCE FOR THROUGH-SPACE ORBITAL INTERACTIONS IN SPIROMETHANOFULLERENES [J].

EIERMANN, M ;

HADDON, RC ;

KNIGHT, B ;

LI, QC ;

MAGGINI, M ;

MARTIN, N ;

OHNO, T ;

PRATO, M ;

SUZUKI, T ;

WUDL, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (15) :1591-1594

[8]

EIERMANN M, 1995, ANGEW CHEM, V107, P1733

[9]

FRISCH MJ, 1993, 92DFT GAUSSIAN

[10] SUPERCONDUCTIVITY AT 18-K IN POTASSIUM-DOPED C-60 [J].

HEBARD, AF ;

ROSSEINSKY, MJ ;

HADDON, RC ;

MURPHY, DW ;

GLARUM, SH ;

PALSTRA, TTM ;

RAMIREZ, AP ;

KORTAN, AR .

NATURE, 1991, 350 (6319) :600-601