Temperature-induced inversion of nanoparticle-stabilized emulsions

被引:199
作者
Binks, BP [1 ]
Murakami, R
Armes, SP
Fujii, S
机构
[1] Univ Hull, Dept Chem, Surfactant & Colloid Grp, Kingston Upon Hull HU6 7RX, N Humberside, England
[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
emulsions; inversion; latex; nanoparticles; wettability;
D O I
10.1002/anie.200501073
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A change for the wetter: The effect of temperature T on the position of a sterically stabilized polystyrene latex particle adsorbed at an oil-water interface is described. Emulsions stabilized by such particle monolayers are oil-in-water at low T and water-in-oil at high T (see scheme). The results are also in line with the predicted change in the wettability of the particles in emulsions. (Figure Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4795 / 4798
页数:4
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