Fe(CN)6-4-doped polypyrrole: a high-capacity and high-rate cathode material for sodium-ion batteries

被引：64

作者：

Zhou, Min ^{[1
]}

Zhu, Limin ^{[1
]}

Cao, Yuliang ^{[2
]}

Zhao, Ruirui ^{[1
]}

Qian, Jianfeng ^{[2
]}

Ai, Xinping ^{[2
]}

Yang, Hanxi ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

[2] Wuhan Univ, Dept Chem, Hubei Key Lab Electrochem Power Sources, Wuhan 430072, Peoples R China

来源：

RSC ADVANCES | 2012年 / 2卷 / 13期

基金：

美国国家科学基金会;

关键词：

ENERGY-STORAGE; LITHIUM-ION; LOW-COST; ELECTRODES; COMPOSITE; INSERTION; NA; LI;

D O I：

10.1039/c2ra20666h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A redox-active Fe(CN)(6)(-4)-doped polypyrrole was synthesized and found to have a remarkable redox capacity of 135 mA h g(-1) in Na+ electrolyte, an excellent rate capability of 1600 mA g(-1) and a strong capacity retention of 85% over 100 cycles, showing great promise for enabling low-cost and environmentally benign Naion batteries for large-scale electric energy storage.

引用

页码：5495 / 5498

页数：4

共 19 条

[1] Carbon microspheres obtained from resorcinol-formaldehyde as high-capacity electrodes for sodium-ion batteries [J].

Alcántara, R ;

Lavela, P ;

Ortiz, GF ;

Tirado, JL .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (04) :A222-A225

[2] Negative electrodes for lithium- and sodium-ion batteries obtained by heat-treatment of petroleum cokes below 1000°C [J].

Alcántara, R ;

Mateos, JMJ ;

Tirado, JL .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (02) :A201-A205

[3] A sodium-ion cell based on the fluorophosphate compound NaVPO4F [J].

Barker, J ;

Saidi, MY ;

Swoyer, JL .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (01) :A1-A4

[4] Structural, Transport, and Electrochemical Investigation of Novel AMSO4F (A = Na, Li; M = Fe, Co, Ni, Mn) Metal Fluorosulphates Prepared Using Low Temperature Synthesis Routes [J].

Barpanda, Prabeer ;

Chotard, Jean-Noel ;

Recham, Nadir ;

Delacourt, Charles ;

Ati, Mohamed ;

Dupont, Loic ;

Armand, Michel ;

Tarascon, Jean-Marie .

INORGANIC CHEMISTRY, 2010, 49 (16) :7401-7413

[5] Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life [J].

Cao, Yuliang ;

Xiao, Lifen ;

Wang, Wei ;

Choi, Daiwon ;

Nie, Zimin ;

Yu, Jianguo ;

Saraf, Laxmikant V. ;

Yang, Zhenguo ;

Liu, Jun .

ADVANCED MATERIALS, 2011, 23 (28) :3155-+

[6] A Sodium Ion Based Organic Radical Battery [J].

Dai, Yang ;

Zhang, Yixiao ;

Gao, Lei ;

Xu, Guofeng ;

Xie, Jingying .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (03) :A22-A24

[7] Electrical Energy Storage for the Grid: A Battery of Choices [J].

Dunn, Bruce ;

Kamath, Haresh ;

Tarascon, Jean-Marie .

SCIENCE, 2011, 334 (6058) :928-935

[8] Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes [J].

Kim, Donghan ;

Kang, Sun-Ho ;

Slater, Michael ;

Rood, Shawn ;

Vaughey, John T. ;

Karan, Naba ;

Balasubramanian, Mahalingam ;

Johnson, Christopher S. .

ADVANCED ENERGY MATERIALS, 2011, 1 (03) :333-336

[9] Na-ion batteries, recent advances and present challenges to become low cost energy storage systems [J].

Palomares, Veronica ;

Serras, Paula ;

Villaluenga, Irune ;

Hueso, Karina B. ;

Carretero-Gonzalez, Javier ;

Rojo, Teofilo .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (03) :5884-5901

[10] Conducting-polymer/iron-redox-couple composite cathodes for lithium secondary batteries [J].

Park, Kyu-Sung ;

Schougaard, Steen B. ;

Goodenough, John B. .

ADVANCED MATERIALS, 2007, 19 (06) :848-+

← 1 2 →