Effect of Nd on the corrosion behaviour of AM50 and AZ91D magnesium alloys in 3.5 wt.% NaCl solution

被引:204
作者
Arrabal, R. [1 ]
Pardo, A. [1 ]
Merino, M. C. [1 ]
Mohedano, M. [1 ]
Casajus, P. [1 ]
Paucar, K. [2 ]
Garces, G. [3 ]
机构
[1] Univ Complutense Madrid, Fac Ciencias Fis, Dept Ciencia Mat, E-28040 Madrid, Spain
[2] Univ Nacl Ingn, Fac Ingn Quim & Text, Lima, Peru
[3] Ctr Nacl Invest Met CSIC, Madrid 28040, Spain
关键词
Magnesium; Polarization; Weight loss; Pitting corrosion; MECHANICAL-PROPERTIES; PURE MAGNESIUM; MICROSTRUCTURE; RESISTANCE; PROTECTION; NEODYMIUM; CHLORIDE; OXIDES;
D O I
10.1016/j.corsci.2011.10.033
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
The corrosion performance of AM50 and AZ91D alloys containing up to 1.5 wt.% Nd was investigated by electrochemical and gravimetric measurements in 3.5 wt.% NaCl at 22 degrees C. The alloys were characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD) and surface potential maps. In Nd-containing alloys, formation of Al2Nd and Al-Mn-Nd intermetallic compounds reduced the volume fraction and modified the morphology of the beta-Mg17Al12 phase. The addition of Nd improved the corrosion resistance of the alloys due to increased passivity of the surface film and suppression of micro-galvanic couples. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:301 / 312
页数:12
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