Na4Co3(PO4)(2)P2O7, a new sodium cobalt phosphate containing a three-dimensional system of large intersecting tunnels

被引：45

作者：

Sanz, F

Parada, C

Amador, U

Monge, MA

Valero, CR

机构：

[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,CAI DIFRACC RAYOS X,E-28040 MADRID,SPAIN

[2] UNIV COMPLUTENSE,FAC CIENCIAS QUIM,DEPT QUIM INORGAN,E-28040 MADRID,SPAIN

[3] CSIC,INST CIENCIA MAT,E-28006 MADRID,SPAIN

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1996年 / 123卷 / 01期

关键词：

D O I：

10.1006/jssc.1996.0161

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of the new Co(II) phosphate Na4Co3(PO4)(2)P2O7 have been isolated and their structure has been determined by X-ray diffraction techniques, This compound crystallizes in the orthorhombic noncentrosymmetric space group Pn2(1)a with a = 18.046(5) Angstrom, b = 6.533(2) Angstrom, c = 10.536(2) Angstrom, and Z = 4, The structure consists of infinite layers with composition (Co3P2O13)(infinity) parallel to the be plane, Interlayer linkages are made via P-O-P bridges of the pyrophosphate groups in such a way that large tunnels extending along the [010] and [001] directions occur between two neighboring sheets, Besides, there also exist channels along the [100] direction crossing the (Co3P2P13)(infinity) layers, A complex scheme of tunnel intersections gives rise to the formation of a three-dimensional channel network which hosts the sodium cations. (C) 1996 Academic Press, Inc.

引用

页码：129 / 139

页数：11