Meso/Macroporous Nitrogen-Doped Carbon Architectures with Iron Carbide Encapsulated in Graphitic Layers as an Efficient and Robust Catalyst for the Oxygen Reduction Reaction in Both Acidic and Alkaline Solutions

被引:559
作者
Xiao, Meiling [1 ]
Zhu, Jianbing [1 ]
Feng, Ligang [2 ]
Liu, Changpeng [1 ]
Xing, Wei [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[2] Chalmers Univ Technol, Dept Appl Phys, SE-41296 Gothenburg, Sweden
基金
中国国家自然科学基金; 国家高技术研究发展计划(863计划);
关键词
electrocatalyst; fuel cells; iron carbide; nitrogen-doped carbon; oxygen reduction reaction; ELECTROCATALYSTS; GRAPHENE; NANOPARTICLES; BATTERIES; SHELL; SIZE;
D O I
10.1002/adma.201500262
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Meso-/macroporous nitrogen-doped carbon architectures with iron carbide encapsulated in graphitic layers are fabricated by a facile approach. This efficient and robust material exhibits superior catalytic performance toward the oxygen reduction reaction in both acidic and alkaline solutions and is the most promising alternative to a Pt catalyst for use in electrochemical energy devices. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:2521 / 2527
页数:7
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