Sp2 C-Dominant N-Doped Carbon Sub-micrometer Spheres with a Tunable Size: A Versatile Platform for Highly Efficient Oxygen-Reduction Catalysts

被引:927
作者
Ai, Kelong [1 ]
Liu, Yanlan [1 ]
Ruan, Changping [1 ]
Lu, Lehui [1 ]
Lu, Gaoqing [2 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[2] Univ Queensland, ARC Ctr Excellence Funct Nanomat, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia
关键词
carbon spheres; nanomaterials; dopamine; controllable synthesis; electrocatalysis; HIGH ELECTROCATALYTIC ACTIVITY; ASSISTED SYNTHESIS; POLYMER; MONODISPERSE; NANOSPHERES; NANOTUBES; DOPAMINE; ARRAYS; ROUTE;
D O I
10.1002/adma.201203923
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A simple, yet versatile strategy to prepare size-controlled and monodisperse carbon sub-micrometer spheres is developed based on the biomolecule dopamine. Unlike traditional carbon materials, the resulting carbon sub-micrometer spheres contain much less sp3 carbon with high-level electroactive nitrogen. Moreover, metal-carbon hybrid sub-micrometer spheres can be easily obtained, and show highly promising catalytic properties in the oxygen-reduction reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:998 / 1003
页数:6
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