The syntheses of C6CH2•- and the corresponding carbenoid cumulene C6CH2 in the gas phase

被引：11

作者：

Dua, S ^{[1
]}

Blanksby, SJ ^{[1
]}

Bowie, JH ^{[1
]}

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 16期

关键词：

D O I：

10.1039/a804070b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ion (C6CH2)(.-) is formed in the gas phase by the process -C=C-C=C-C=CH2OEt --> (C6CH2)(.-) + EtO., and charge stripping of the product radical anion yields the carbenoid neutral C6CH2; this can be either a singlet (the ground state), which is best represented as the carbene :C=C=C=C=C=C=CH2, or a triplet; the adiabatic electron affinity and the dipole moment of the carbenoid neutral are calculated to be 2.82 eV and 7.33 D respectively.

引用

页码：1767 / 1768

页数：2

共 22 条

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