A SERS-activated nanocrystalline Pd substrate and its nanopatterning leading to biochip fabrication

被引:32
作者
Bhuvana, Thiruvelu
Kulkarni, Giridhar U.
机构
[1] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
[2] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, DST Unit Nanosci, Bangalore 560064, Karnataka, India
关键词
electron-beam lithography; nanocrystalline materials; palladium; patterning; Raman spectroscopy;
D O I
10.1002/smll.200701075
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanocrystalline metallic Pd films have been produced by thermolysis of Pd hexadecanethiolate deposited on a Si surface. The particle size was in the range of 50-60 nm based on electron and atomic force microscopy. The Pd surface produced was found to be surface-enhanced Raman scattering (SERS) active with an enhancement factor of approximate to 10(5). The electron-resist behavior of Pd thiolate is exploited in conceptualizing a prototype chip with patterned Pd regions that are SERS active, called "SERS bits", which host different biomolecules.
引用
收藏
页码:670 / 676
页数:7
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