New ionic liquids with tris(perfluoroalkyl)trifluorophosphate (FAP) anions

被引：249

作者：

Ignat'ev, NV

Welz-Biermann, U

Kucheryna, A

Bissky, G

Willner, H

机构：

[1] Merck KGaA, New Ventures Mat, D-64293 Darmstadt, Germany

[2] Berg Univ Gesamthsch Wuppertal, D-47097 Wuppertal, Germany

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2005年 / 126卷 / 08期

关键词：

ionic liquids; tris(perfluoroalkyl)trifluorophosphate; viscosity; conductivity; electrochemical stability;

D O I：

10.1016/j.jfluchem.2005.04.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of new ionic liquids with tris(perfluoroalkyl)trifluorophosphate (FAP) anions is described. The physico-chemical properties (conductivity, viscosity, electrochemical and thermal stability) of this new generation of ionic liquids (molten salts) are discussed. FAP-ionic liquids show an excellent hydrolytic stability, low viscosity and high electrochemical and thermal stability that makes them attractive for use in electrochemical devices and as a new media for application in modern technologies and chemical synthesis. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1150 / 1159

页数：10