New nanostructured TiO2 for direct electrochemistry and glucose sensor applications

被引:413
作者
Bao, Shu-Juan [1 ]
Li, Chang Ming [1 ]
Zang, Jian-Feng [2 ]
Cui, Xiao-Qiang [1 ]
Qiao, Yan [1 ]
Guo, Jun [3 ]
机构
[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore
[2] Nanyang Technol Univ, Sch Elect & Elect Engn, Singapore 639798, Singapore
[3] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
关键词
D O I
10.1002/adfm.200700728
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new, slack, and uniformly porous TiO2 material is synthesized by a simple, carbon nanotube (CNT) template-assisted I hydrothermal method and is further explored for protein immobilization and biosensing. Results demonstrate that the material I has a large specific surface area and a unique nanostructure with a uniform pore-size distribution. Glucose oxidase (GOD) immobilized on the material exhibits facile, direct electrochemistry and good electrocatalytic performance without any electron mediator. The fabricated glucose oxidase sensor shows good stability and high sensitivity, which indicates that the slack porous TiO2 is an attractive material for use in the fabrication of biosensors, particularly enzymatic sensors, because of its direct electrochemistry, high specific surface area, and unique nanostructure for efficient immobilization of biomolecules.
引用
收藏
页码:591 / 599
页数:9
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