Preparation of ultrafine nickel powder and its catalytic dehydrogenation activity

被引:111
作者
Gao, JZ [1 ]
Guan, F [1 ]
Zhao, YC [1 ]
Yang, W [1 ]
Ma, YJ [1 ]
Lu, XQ [1 ]
Hou, JG [1 ]
Kang, JW [1 ]
机构
[1] NW Normal Univ, Inst Chem, Lanzhou 730070, Peoples R China
关键词
preparation; ultrafine nickel powder; catalytic dehydrogenation activity;
D O I
10.1016/S0254-0584(01)00275-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanocrystalline nickel powders were prepared from aqueous solution by reducing their corresponding metal salts under suitable conditions. The experimental conditions including the types and concentration of Protective agents, feeding order and the PH of the solution that influence, the average particle size were studied in detail. X-ray powder diffraction patterns show that the nickel powder is cubic crystallite. The average particle size of the ultrafine nickel powder is 50 nm. In addition, we also studied the effect of particle size in liquid phase dehydrogenation of 2-butanol. The results show that the smaller particle size is favored of increasing catalytic activity. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:215 / 219
页数:5
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