Efficient synthesis of pentakis- and tris(pyridine) ligands

被引:29
作者
Uenal, E. Alper [1 ]
Wiedemann, Dennis [1 ]
Seiffert, Josef [1 ]
Boyd, John P. [1 ]
Grohmann, Andreas [1 ]
机构
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
关键词
Tripodal ligand; Tetrapodal pentadentate ligand; Oligopyridines; Ligand design; Nucleophilic substitution; GENERATING HYDROGEN; COMPLEXES; REACTIVITY; CATALYST; WATER;
D O I
10.1016/j.tetlet.2011.10.131
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A variety of substituted tris(pyridyl) frameworks, as well as a pentakis(pyridine) system, are conveniently accessible in a one-pot synthesis, which consists of two sequential nucleophilic aromatic substitutions, employing substituted pyridine precursors. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:54 / 55
页数:2
相关论文
共 12 条
[1]  
Bechlars B, 2010, NAT CHEM, V2, P362, DOI [10.1038/NCHEM.585, 10.1038/nchem.585]
[2]   INTERACTION OF PALLADIUM(II) ACETATE WITH SUBSTITUTED PYRIDINES, INCLUDING A CYCLOMETALLATION REACTION AND THE STRUCTURE OF [PD(MESO-[(PY)PHMEC]2-C5H3N)(O2CME)][O2CME].3H2O [J].
CANTY, AJ ;
MINCHIN, NJ ;
SKELTON, BW ;
WHITE, AH .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10) :2205-2210
[3]   Synthesis of methylene- and methine-bridged oligopyridines [J].
Dyker, G ;
Muth, O .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (21) :4319-4322
[4]   Hydrogen atom abstraction by a mononuclear ferric hydroxide complex: Insights into the reactivity of lipoxygenase [J].
Goldsmith, Christian R. ;
Stack, T. Daniel P. .
INORGANIC CHEMISTRY, 2006, 45 (15) :6048-6055
[5]   Tetrapodal pentadentate ligands: Single site reactivity and bond activation in iron(II) complexes [J].
Grohmann, Andreas .
DALTON TRANSACTIONS, 2010, 39 (06) :1432-1440
[6]   A molecular molybdenum-oxo catalyst for generating hydrogen from water [J].
Karunadasa, Hemamala I. ;
Chang, Christopher J. ;
Long, Jeffrey R. .
NATURE, 2010, 464 (7293) :1329-1333
[7]  
López JP, 2002, CHEM-EUR J, V8, P5709
[8]   First-row transition-metal complexes of a new pentadentate ligand, α,α,α′,α′-tetra(pyrazolyl)lutidine [J].
Morin, Tyler J. ;
Bennett, Brian ;
Lindeman, Sergey V. ;
Gardinier, James R. .
INORGANIC CHEMISTRY, 2008, 47 (17) :7468-7470
[9]   A state-of-the-art cyanation of aryl bromides:: A novel and versatile copper catalyst system inspired by nature [J].
Schareina, Thomas ;
Zapf, Alexander ;
Maegerlein, Wolfgang ;
Mueller, Nikolaus ;
Beller, Matthias .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (21) :6249-6254
[10]   Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water [J].
Sun, Yujie ;
Bigi, Julian P. ;
Piro, Nicholas A. ;
Tang, Ming Lee ;
Long, Jeffrey R. ;
Chang, Christopher J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (24) :9212-9215