Synthesis of Dithienogermole-Containing π-Conjugated Polymers and Applications to Photovoltaic Cells

被引:66
作者
Ohshita, Joji [1 ]
Hwang, Yong-Mook [1 ]
Mizumo, Tomonobu [1 ]
Yoshida, Hiroto [1 ]
Ooyama, Yousuke [1 ]
Harima, Yutaka [1 ]
Kunugi, Yoshihito [2 ]
机构
[1] Hiroshima Univ, Dept Appl Chem, Grad Sch Engn, Higashihiroshima 7398527, Japan
[2] Tokai Univ, Dept Appl Chem, Fac Engn, Hiratsuka, Kanagawa 2591292, Japan
关键词
BAND-GAP; DITHIENOSILOLE UNITS; MOLECULAR DESIGN; HIGH-MOBILITY; SOLAR-CELLS; POLYTHIOPHENES; OLIGOMERS; ACCEPTOR; DONOR; SEMICONDUCTORS;
D O I
10.1021/om200081b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dithienogermole-containing pi-conjugated polymers were prepared by the Stille coupling reactions of distannyldithienogermole and dibromoarenes. The polymers exhibit optical properties similar to those of the previously reported silicon analogues and are usable as the active materials for bulk heterojunction-type organic photovoltaic cells as blends with PC(70)BM.
引用
收藏
页码:3233 / 3236
页数:4
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