Preparation, characterization, and X-ray crystal structure of a one-dimensional calcium-based coordination polymer with strong blue fluorescent emission

被引：47

作者：

Yuan, RX

Xiong, RG

Chen, ZF

You, XZ ^{[1
]}

Peng, SM

Lee, GH

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 08期

基金：

中国国家自然科学基金;

关键词：

calcium complex; crystal structure; hydrothermal synthesis; blue fluorescent emission;

D O I：

10.1016/S1387-7003(01)00242-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of 4-cyanobenzoic acid with Ca(ClO4)(2) . 6H(2)O yields the one-dimensional calcium-based coordination polymer [Ca(L)(2)(H2O)2](n) 1 (where L = 4-cyanobenzoic acid) with strong blue fluorescent emission, and its solid-state structure has been characterized by X-ray single-crystal diffraction studies. Crystal data for 1: monoclinic, space group P2/n, a = 7.154 (2), b = 16.402 (3), c = 7.549 (2) Angstrom; beta = 115.83 (2)degrees, Z = 2; R = 0.0536 for 1410 independent reflections with I > 2 alpha (I). (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：430 / 433

页数：4