A giant supramolecular light-harvesting antenna-acceptor composite

被引：55

作者：

Furutsu, D ^{[1
]}

Satake, A ^{[1
]}

Kobuke, Y ^{[1
]}

机构：

[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 13期

关键词：

D O I：

10.1021/ic050029+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A giant light-harvesting antenna-acceptor composite was constructed by heterodimerization of imidazolylmanganese(III)porphyrin to molecular terminals of the zinc porphyrin array composed of meso-meso linked bis(imidazolylzincporphyrin). Fluorescence quenching titration indicated that the terminal imidazolylmanganase-(III)porphyrin quenched excited zinc porphyrin separated by a large number of intervening porphyrins and that the meso-meso linked bis(imidazolylzincporphyrin) array was an efficient light-harvesting antenna.

引用

页码：4460 / 4462

页数：3

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