A phthalocyanine clathrate of cubic symmetry containing interconnected solvent-filled voids of nanometer dimensions

被引：57

作者：

McKeown, NB ^{[1
]}

Makhseed, S

Msayib, KJ

Ooi, LL

Helliwell, M

Warren, JE

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales

[2] Kuwait Univ, Dept Chem, Safat 13060, Kuwait

[3] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[4] CCLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 46期

关键词：

clathrates; crystal engineering; microporous materials; nanostructures; phthalocyanines;

D O I：

10.1002/anie.200502668

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A void apart! A clathrate based on zinc octa(2,6-diisopropylphenoxy)phthalocyanine contains solvent-filled voids of exceptionally large volume (> 8 nm3; see picture for the packing arrangement). Each nanovoid is enclosed by a cubic assembly of six phthalocyanine molecules and contains 18 molecules of water and an estimated 65 molecules of acetone, which may be exchanged for methanol or water molecules without loss of order. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7546 / 7549

页数：4

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