Synthesis and nonlinear optical characterization of nanostructured gold/polymer composites and suspensions

被引:18
作者
Gonsalves, KE
Carlson, G
Chen, X
Gayen, SK
Perez, R
JoseYacaman, M
机构
[1] UNIV CONNECTICUT,DEPT CHEM,STORRS,CT 06269
[2] STEVENS INST TECHNOL,DEPT PHYS & ENGN PHYS,HOBOKEN,NJ 07030
[3] UNIV NACL AUTONOMA MEXICO,INST FIS,LAB CUERNAVACA,CUERNAVACA 62191,MORELOS,MEXICO
来源
NANOSTRUCTURED MATERIALS | 1996年 / 7卷 / 03期
关键词
D O I
10.1016/0965-9773(96)00009-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanometric gold particles were synthesized by a liquid/liquid phase-transfer reaction. Composites of these particles were prepared by free-radical polymerization of suspensions of the particles in styrene and methyl methacrylate monomer. Concentrations of 1.0, 1.3, and 4.4 mg/ml were prepared, with no noticeable agglomeration of particles during processing. These composites and toluene suspensions (0.18 mg/ml) showed a linear absorption peek at 530 nm, which is characteristic of nanosized gold. High-resolution electron microscopy measurement showed that the particle diameters varied from 5 to 10 nm. Degenerate four-wave mixing experiments at 532 nm yielded, on 10-micron films, a maximum value of 1.0 x 10(-10) e.s.u. for the third-order nonlinear optical susceptibility. The toluene suspension had a susceptibility of 7.7 x 10(-12) e.s.u.
引用
收藏
页码:293 / 303
页数:11
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