Synthesis and electropolymerisation of 1,1′-bis(5-oligothienyl)ferrocenes:: poly(oligothiophene-ferrocene)-modified electrodes

被引：33

作者：

Higgins, SJ

Jones, CL

Francis, SM

机构：

[1] Univ Liverpool, Dept Chem, Donnan & Robert Robinson Labs, Liverpool L69 7ZD, Merseyside, England

[2] Univ Liverpool, Surface Sci Res Ctr, Liverpool L69 3BX, Merseyside, England

来源：

SYNTHETIC METALS | 1999年 / 98卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

Stille coupling; ferrocenes; electropolymerisation; oligothiophenes; XPS;

D O I：

10.1016/S0379-6779(98)00189-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Stille coupling between 1,1'-bis(tributylstannyl)ferrocene and 5-iodo-oligothiophenes has been employed to prepare 1,1'-bis(5-oligothienyl)ferrocenes, which have been electropolymerised to afford films of poly(oligothiophene-ferrocene)s with unusual redox properties. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：211 / 214

页数：4

相关论文

共 25 条

[11] AN ELLIPSOMETRIC STUDY OF THE NUCLEATION AND GROWTH OF POLYTHIOPHENE FILMS [J].

HAMNETT, A ;

HILLMAN, AR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (10) :2517-2524

[12] METAL LIGAND BOND CONTRACTION AND POSSIBLE SPIN-ORBIT INDUCED JAHN-TELLER DISTORTION IN IRON(III) DIALKYLDITHIOCARBAMATE CROSSOVER SYSTEM [J].

HEALY, PC ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (22) :1446-+

[13] THIOPHENE-ALKYLTHIOPHENE COPOLYMERS FROM SUBSTITUTED DIALKYLOLIGOTHIOPHENES [J].

HENDERSON, PT ;

COLLARD, DM .

CHEMISTRY OF MATERIALS, 1995, 7 (10) :1879-1889

[14]

HERRMAN WA, 1987, Patent No. 3703771

[15] Improved preparation of polybenzo[c]thiophene-modified electrodes employing p-toluenesulfonate as dopant anion [J].

Higgins, SJ ;

Jones, C ;

King, G ;

Slack, KHD ;

Petidy, S .

SYNTHETIC METALS, 1996, 78 (02) :155-159

[16] Conjugated polymers incorporating pendant functional groups - synthesis and characterisation [J].

Higgins, SJ .

CHEMICAL SOCIETY REVIEWS, 1997, 26 (04) :247-257

[17] MAGNETIC-PROPERTIES OF FERROCENE-BASED CONJUGATED POLYMERS [J].

HMYENE, M ;

YASSAR, A ;

ESCORNE, M ;

PERCHERONGUEGAN, A ;

GARNIER, F .

ADVANCED MATERIALS, 1994, 6 (7-8) :564-568

[18] SYNTHESIS, CHARACTERIZATION AND ELECTROPOLYMERIZATION OF FERROCENE MONOMERS WITH ANILINE AND PHENOL SUBSTITUENTS [J].

HORWITZ, CP ;

SUHU, NY ;

DAILEY, GC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 324 (1-2) :79-91

[19] ELECTROCHEMICAL SYNTHESIS OF FERROCENE-FUNCTIONALIZED POLYPYRROLE FILMS [J].

INAGAKI, T ;

HUNTER, M ;

YANG, XQ ;

SKOTHEIM, TA ;

OKAMOTO, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (02) :126-127

[20]

MACEACHERN A, 1988, TETRAHEDRON, V44, P2403