Development of a highly α-regioselective indium-mediated allylation reaction in water

被引：42

作者：

Loh, TP ^{[1
]}

Tan, KT ^{[1
]}

Yang, JY ^{[1
]}

Xiang, CL ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 49期

关键词：

D O I：

10.1016/S0040-4039(01)01883-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Linear alpha homoallylic alcohol adducts were obtained with high regioselectivities in moderate to good yields using allylic indium reagents in the presence of 10 M water. The exceptionally high regioselectivities observed were neither steric nor electronic in origin from the results presented in this paper. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：8701 / 8703

页数：3

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