A monostyryl-boradiazaindacene (BODIPY) derivative as colorimetric and fluorescent probe for cyanide ions

被引:292
作者
Ekmekci, Zeynep [2 ]
Yilmaz, M. Deniz [2 ]
Akkaya, Engin U. [1 ]
机构
[1] Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey
[2] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
关键词
D O I
10.1021/ol702823u
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We developed a novel boradiazaindacene derivative to detect cyanide ions in solution at micromolar concentrations. This structurally simple chemosensor displays a large decrease in emission intensity and a reversible color change from red to blue on contact with cyanide ions. Highly fluorescent polymeric films can be obtained by doping with the chemosensor. Such polymeric materials can be used for the sensing of the cyanide ions in polymer matrices.
引用
收藏
页码:461 / 464
页数:4
相关论文
共 43 条
[1]   What anions do to N-H-containing receptors [J].
Amendola, Valeria ;
Esteban-Gomez, David ;
Fabbrizzi, Luigi ;
Licchelli, Maurizio .
ACCOUNTS OF CHEMICAL RESEARCH, 2006, 39 (05) :343-353
[2]  
[Anonymous], 1999, ULLMANS ENCY IND CHE
[3]  
[Anonymous], 1994, TOPICS FLUORESCENCE
[4]   Neutral anion receptors: design and application [J].
Antonisse, MMG ;
Reinhoudt, DN .
CHEMICAL COMMUNICATIONS, 1998, (04) :443-448
[5]   Luminescence lifetime-based sensor for cyanide and related anions [J].
Anzenbacher, P ;
Tyson, DS ;
Jursíková, K ;
Castellano, FN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) :6232-6233
[6]   Water soluble distyryl-boradiazaindacenes as efficient photosensitizers for photodynamic therapy [J].
Atilgan, Serdar ;
Ekmekci, Zeynep ;
Dogan, A. Lale ;
Guc, Dicle ;
Akkaya, Engin U. .
CHEMICAL COMMUNICATIONS, 2006, (42) :4398-4400
[7]   Enhanced fluorescence cyanide detection at physiologically lethal levels: Reduced ICT-based signal transduction [J].
Badugu, R ;
Lakowicz, JR ;
Geddes, CD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3635-3641
[8]  
Baskin S.I., 1997, TXB MILITARY MED MED, P271
[9]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
[10]  
2-G