Programming a gold nanocrystal to recognize and selectively bind a molecular substrate in solution

被引：34

作者：

Aherne, D ^{[1
]}

Rao, SN ^{[1
]}

Fitzmaurice, D ^{[1
]}

机构：

[1] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Dublin 4, Ireland

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1999年 / 103卷 / 11期

关键词：

D O I：

10.1021/jp9832950

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Gold nanocrystals stabilized by a chemisorbed mixture of a long-chain alkane thiol, namely dodecanethiol (95 %), and a long-chain dodecanethiol incorporating a receptor, namely 12-mercaptododecyl-1-uracil (5%), have been prepared. In solution, these nanocrystals recognize and selectively bind a long-chain alkane incorporating a complementary substrate, namely, N,N'-2,6-pyridinediylbis[undecamide].

引用

页码：1821 / 1825

页数：5

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