Production of 1,3-propanediol by hydrogenolysis of glycerol catalyzed by Pt/WO3/ZrO2

被引:193
作者
Kurosaka, Tadahiro [1 ]
Maruyama, Hideyuki [2 ]
Naribayashi, Ikuya [2 ]
Sasaki, Yoshiyuki [1 ]
机构
[1] AIST, Biomass Technol Res Ctr, Hiroshima 7370197, Japan
[2] Sakamoto Yakuhin Kogyo Co Ltd, Izumiotsu City, Osaka, Japan
关键词
1,3-propanediol; glycerol; hydrogenolysis; noble metal; tungsten oxide;
D O I
10.1016/j.catcom.2007.11.034
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Glycerol hydrogenolysis was catalyzed by Pt/WO3/ZrO2 to give 1,3-propanediol (1,3-PD) in the yields up to 24%. The catalytic activities and the selectivity toward 1,3-PD were remarkably affected by the type of support, loaded noble metal (NM) and the preparation/impregnation procedure. Controlled experiments show that the active site of catalyst for the formation of 1,3-PD may be the Pt over WO3 supported on ZrO2. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1360 / 1363
页数:4
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