Production of 1,3-propanediol by hydrogenolysis of glycerol catalyzed by Pt/WO3/ZrO2

被引：196

作者：

Kurosaka, Tadahiro ^{[1
]}

Maruyama, Hideyuki ^{[2
]}

Naribayashi, Ikuya ^{[2
]}

Sasaki, Yoshiyuki ^{[1
]}

机构：

[1] AIST, Biomass Technol Res Ctr, Hiroshima 7370197, Japan

[2] Sakamoto Yakuhin Kogyo Co Ltd, Izumiotsu City, Osaka, Japan

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 06期

关键词：

1,3-propanediol; glycerol; hydrogenolysis; noble metal; tungsten oxide;

D O I：

10.1016/j.catcom.2007.11.034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Glycerol hydrogenolysis was catalyzed by Pt/WO3/ZrO2 to give 1,3-propanediol (1,3-PD) in the yields up to 24%. The catalytic activities and the selectivity toward 1,3-PD were remarkably affected by the type of support, loaded noble metal (NM) and the preparation/impregnation procedure. Controlled experiments show that the active site of catalyst for the formation of 1,3-PD may be the Pt over WO3 supported on ZrO2. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：1360 / 1363

页数：4

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