Thermal conductivity and interfacial resistance in single-wall carbon nanotube epoxy composites

被引:323
作者
Bryning, MB [1 ]
Milkie, DE [1 ]
Islam, MF [1 ]
Kikkawa, JM [1 ]
Yodh, AG [1 ]
机构
[1] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA
基金
美国国家科学基金会; 美国国家航空航天局;
关键词
D O I
10.1063/1.2103398
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report thermal conductivity measurements of purified single-wall carbon nanotube (SWNT) epoxy composites prepared using suspensions of SWNTs in N-N-Dimethylformamide (DMF) and surfactant stabilized aqueous SWNT suspensions. Thermal conductivity enhancement is observed in both types of composites. DMF-processed composites show an advantage at SWNT volume fractions between phi similar to 0.001 to 0.005. Surfactant processed samples, however, permit greater SWNT loading and exhibit larger overall enhancement (64 +/- 9)% at phi similar to 0.1. The enhancement differences are attributed to a ten-fold larger SWNT/solid-composite interfacial thermal resistance in the surfactant-processed composites compared to DMF-processed composites. The interfacial resistance is extracted from the volume fraction dependence of the thermal conductivity data using effective medium theory. [C. W. Nan, G. Liu, Y. Lin, and M. Li, Appl. Phys. Lett. 85, 3549 (2004)]. (C) 2005 American Institute of Physics.
引用
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页码:1 / 3
页数:3
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