Large-Scale Exfoliation of Inorganic Layered Compounds in Aqueous Surfactant Solutions

被引:1015
作者
Smith, Ronan J. [1 ,2 ]
King, Paul J. [1 ,2 ]
Lotya, Mustafa [1 ,2 ]
Wirtz, Christian [1 ,2 ]
Khan, Umar [1 ,2 ]
De, Sukanta [1 ,2 ]
O'Neill, Arlene [1 ,2 ]
Duesberg, Georg S. [2 ,3 ]
Grunlan, Jaime C. [4 ]
Moriarty, Gregory [4 ]
Chen, Jun [5 ]
Wang, Jiazhao [6 ]
Minett, Andrew I. [7 ]
Nicolosi, Valeria [8 ]
Coleman, Jonathan N. [1 ,2 ]
机构
[1] Trinity Coll Dublin, Sch Phys, Dublin 2, Ireland
[2] Trinity Coll Dublin, CRANN, Dublin 2, Ireland
[3] Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland
[4] Texas A&M Univ, Dept Mech Engn, College Stn, TX 77843 USA
[5] Univ Wollongong, Intelligent Polymer Res Inst, ARC Ctr Excellence Electromat Sci, AIIM Facil, Wollongong, NSW 2522, Australia
[6] Univ Wollongong, Inst Superconducting & Elect Mat, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia
[7] Univ Sydney, Lab Sustainable Technol, Sch Chem & Biomol Engn, Sydney, NSW 2006, Australia
[8] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
基金
欧洲研究理事会; 爱尔兰科学基金会;
关键词
BORON-NITRIDE; CARBON NANOTUBES; INTERCALATION; MOS2; GRAPHENE; NANOSHEETS; ENERGY;
D O I
10.1002/adma.201102584
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A method to exfoliate MoS2 in large quantities in surfactant-water solutions is described. The layered material tends to be exfoliated as dispersions of thin, relatively defect-free flakes with lateral sizes of hundreds of nanometers. This method can be extended to a range of other layered compounds. The dispersed flakes can be mixed with nanotubes or graphene to greate functional hybrid materials.
引用
收藏
页码:3944 / +
页数:6
相关论文
共 41 条
[1]   Toward pillared layered metal sulfides. Intercalation of the chalcogenide clusters Co(6)Q(8)(PR(3))(6) (Q=S, Se, and Te and R=alkyl) into MoS2 [J].
Bissessur, R ;
Heising, J ;
Hirpo, W ;
Kanatzidis, M .
CHEMISTRY OF MATERIALS, 1996, 8 (02) :318-&
[2]  
Bohren C. F., 1998, ABSORPTION SCATTERIN, DOI 10.1002/9783527618156
[3]   Preparation and Characterization of Flexible Asymmetric Supercapacitors Based on Transition-Metal-Oxide Nanowire/Single-Walled Carbon Nanotube Hybrid Thin-Film Electrodes [J].
Chen, Po-Chiang ;
Shen, Guozhen ;
Shi, Yi ;
Chen, Haitian ;
Zhou, Chongwu .
ACS NANO, 2010, 4 (08) :4403-4411
[4]   Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].
Coleman, Jonathan N. ;
Lotya, Mustafa ;
O'Neill, Arlene ;
Bergin, Shane D. ;
King, Paul J. ;
Khan, Umar ;
Young, Karen ;
Gaucher, Alexandre ;
De, Sukanta ;
Smith, Ronan J. ;
Shvets, Igor V. ;
Arora, Sunil K. ;
Stanton, George ;
Kim, Hye-Young ;
Lee, Kangho ;
Kim, Gyu Tae ;
Duesberg, Georg S. ;
Hallam, Toby ;
Boland, John J. ;
Wang, Jing Jing ;
Donegan, John F. ;
Grunlan, Jaime C. ;
Moriarty, Gregory ;
Shmeliov, Aleksey ;
Nicholls, Rebecca J. ;
Perkins, James M. ;
Grieveson, Eleanor M. ;
Theuwissen, Koenraad ;
McComb, David W. ;
Nellist, Peter D. ;
Nicolosi, Valeria .
SCIENCE, 2011, 331 (6017) :568-571
[5]   Are There Fundamental Limitations on the Sheet Resistance and Transmittance of Thin Graphene Films? [J].
De, Sukanta ;
Coleman, Jonathan N. .
ACS NANO, 2010, 4 (05) :2713-2720
[6]  
Ding ZF, 2001, ADV MATER, V13, P797, DOI 10.1002/1521-4095(200106)13:11<797::AID-ADMA797>3.0.CO
[7]  
2-U
[8]   New directions for low-dimensional thermoelectric materials [J].
Dresselhaus, Mildred S. ;
Chen, Gang ;
Tang, Ming Y. ;
Yang, Ronggui ;
Lee, Hohyun ;
Wang, Dezhi ;
Ren, Zhifeng ;
Fleurial, Jean-Pierre ;
Gogna, Pawan .
ADVANCED MATERIALS, 2007, 19 (08) :1043-1053
[9]   Synthesis of molybdenum disulfide (MoS2) for lithium ion battery applications [J].
Feng, Chuanqi ;
Ma, Jun ;
Li, Hua ;
Zeng, Rong ;
Guo, Zaiping ;
Liu, Huakun .
MATERIALS RESEARCH BULLETIN, 2009, 44 (09) :1811-1815
[10]   Solution-processed anodes from layer-structure materials for high-efficiency polymer light-emitting diodes [J].
Frey, GL ;
Reynolds, KJ ;
Friend, RH ;
Cohen, H ;
Feldman, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (19) :5998-6007