A mild thermal and acid-catalyzed rearrangement of O-aryl ethers into ortho-hydroxy arenes

被引：31

作者：

Goldberg, FW ^{[1
]}

Magnus, P ^{[1
]}

Turnbull, R ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 20期

关键词：

D O I：

10.1021/ol051943+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

graph An unusual rearrangement of an O-aryl ether to an ortho-hydroxyaryl system was discovered during our studies on the synthesis of diazonamide A. We discuss the exploration of this rearrangement under mild thermal and both Bronsted and Lewis acid-catalyzed conditions.

引用

页码：4531 / 4534

页数：4

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