Structure of the THF solvate of tetramesityldisilene

被引：15

作者：

Wind, M ^{[1
]}

Powell, DR ^{[1
]}

West, R ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 26期

关键词：

D O I：

10.1021/om960753n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray crystal structure of Mes(2)Si=SiMes(2) . THF (1 . THF) has been determined The THF molecule is not coordinated to silicon, The two Mes(2)Si units are twisted relative to one another by 13 degrees, while the arrangement at each silicon is coplanar, This conformation differs fi om that found for 1 . C7H8 (12 degrees twist, 18 degrees pyramidalization) and unsolvated 1 (3 degrees twist, 12, 14 degrees pyramidalization).

引用

页码：5772 / 5773

页数：2

共 10 条

[1]

APELOIG Y, 1989, CHEM ORGANIC SILICON, P129

[2]

CHAUBON MA, 1996, J MAIN GROUP MET CHE, V19, P145

[3] REACTION OF A STABLE SILYLENE WITH COVALENT AZIDES - A NEW SYNTHESIS FOR SILAIMINES [J].