Boron as a bridging ligand

被引：53

作者：

Braunschweig, H ^{[1
]}

Whittell, GR ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2005年 / 11卷 / 21期

关键词：

boron; coordination modes; Lewis acids; transition metals;

D O I：

10.1002/chem.200500368

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Lewis acidity of [(eta(5)-C5R5)Fe(CO),(BX2)] (1: R=H, X=Cl) and the robust nature of the constituent Fe-B bond have been demonstrated by reaction with 4-methylpyridine to yield the corresponding Lewis acid-base adduct. These properties have subsequently been utilised in the construction of heterodinuclear bridging borylene, bridging boryl and mu(2)-boride complexes from analogues 3 (R=Me, X=Br) and 5 (R=Me, X=Cl). All the bimetallic species so formed exhibited unprecedented coordination modes for boron.

引用

页码：6128 / 6133

页数：6

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