Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

被引:90
作者
Aromí, G
Parsons, S
Wernsdorfer, W
Brechin, EK
McInnes, EJL
机构
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[2] Univ Barcelona, Fac Quim, Dept Quim Inorgan, E-08028 Barcelona, Spain
[3] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
[4] CNRS, Lab Louis Neel, F-38042 Grenoble, France
关键词
D O I
10.1039/b510097f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ferromagnetic exchange between the ten Ni2+ ions in the complex [Ni-10(tmp)(2)(N-3)(8)(acac)(6)(MeOH)(6)] leads to a spin ground state of S = 10; single crystal M vs. H studies reveal the temperature and sweep rate dependent hysteresis loops expected for a single-molecule magnet.
引用
收藏
页码:5038 / 5040
页数:3
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