A new manganese cluster topology capable of yielding high-spin species: mixed-valence [Mn-7(OH)(3)Cl-3(hmp)(9)](2+) with S>=10

被引：96

作者：

Bolcar, MA

Aubin, SMJ

Folting, K

Hendrickson, DN

Christou, G

机构：

[1] UNIV CALIF SAN DIEGO, DEPT CHEM 0358, LA JOLLA, CA 92093 USA

[2] INDIANA UNIV, DEPT CHEM, BLOOMINGTON, IN 47405 USA

[3] INDIANA UNIV, CTR MOL STRUCT, BLOOMINGTON, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a703007j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between MnCl2.4H(2)O, Hhmp (Hhmp = 2-hydroxymethylpyridine) and NEt4MnO4 in MeCN gives NEt4[Mn-7(OH)(3)Cl-3(hmp)(9)]Cl[MnCl4] 1; the 4 Mn-II, 3 Mn-III cation comprises a Mn-6 hexagon containing a central Mn ion, and it possesses a S greater than or equal to 10 ground state.

引用

页码：1485 / 1486

页数：2

共 22 条

[1] Distorted MnIVMn3III cubane complexes as single-molecule magnets
Aubin, SMJ
Wemple, MW
Adams, DM
Tsai, HL
Christou, G
Hendrickson, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (33) : 7746 - 7754
[2] THE SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A CYCLIC DODECANUCLEAR NICKEL-COMPLEX
BLAKE, AJ
GRANT, CM
PARSONS, S
RAWSON, JM
WINPENNY, REP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) : 2363 - 2364
[3] SPECTROSCOPIC AND REACTIVITY STUDIES OF A COPPER-CONTAINING METALLACROWN
BLAKE, AJ
GOULD, RO
GRANT, CM
MILNE, PEY
REED, D
WINPENNY, REP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (02): : 195 - 197
[4] NEW ROUTES TO COPPER-LANTHANOID COMPLEXES .1. VIA A METALLOMACROCYCLE
BLAKE, AJ
GOULD, RO
MILNE, PEY
WINPENNY, REP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (20) : 1453 - 1455
[5] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE
BROWN, ID
ALTERMATT, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG): : 244 - 247
[6] A CYCLIC HEXAIRON(III) COMPLEX WITH AN OCTAHEDRALLY COORDINATED SODIUM-ION AT THE CENTER, AN EXAMPLE OF THE [12]METALLACROWN-6 STRUCTURE TYPE
CANESCHI, A
CORNIA, A
LIPPARD, SJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (04): : 467 - 469
[7] PREPARATION, CRYSTAL-STRUCTURE, AND MAGNETIC-PROPERTIES OF AN OLIGONUCLEAR COMPLEX WITH 12 COUPLED SPINS AND AN S=12 GROUND-STATE
CANESCHI, A
GATTESCHI, D
LAUGIER, J
REY, P
SESSOLI, R
ZANCHINI, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (09) : 2795 - 2799
[8] MAGNETIC-PROPERTIES OF AN OCTANUCLEAR IRON(III) CATION
DELFS, C
GATTESCHI, D
PARDI, L
SESSOLI, R
WIEGHARDT, K
HANKE, D
[J]. INORGANIC CHEMISTRY, 1993, 32 (14) : 3099 - 3103
[9] HIGH-SPIN MOLECULES - UNUSUAL MAGNETIC-SUSCEPTIBILITY RELAXATION EFFECTS IN [MN12O12(O(2)CET)(16)(H2O)(3)] (S=9) AND THE ONE-ELECTRON REDUCTION PRODUCT (PPH4)[MN12O12(O(2)CET)(16)(H2O)(4)] (S=19/2)
EPPLEY, HJ
TSAI, HL
DEVRIES, N
FOLTING, K
CHRISTOU, G
HENDRICKSON, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) : 301 - 317
[10] Eppley HJ, 1995, MOL CRYST LIQ CRYS A, V273, pA159

← 1 2 3 →