A new manganese cluster topology capable of yielding high-spin species: mixed-valence [Mn-7(OH)(3)Cl-3(hmp)(9)](2+) with S>=10

被引：96

作者：

Bolcar, MA

Aubin, SMJ

Folting, K

Hendrickson, DN

Christou, G

机构：

[1] UNIV CALIF SAN DIEGO, DEPT CHEM 0358, LA JOLLA, CA 92093 USA

[2] INDIANA UNIV, DEPT CHEM, BLOOMINGTON, IN 47405 USA

[3] INDIANA UNIV, CTR MOL STRUCT, BLOOMINGTON, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a703007j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between MnCl2.4H(2)O, Hhmp (Hhmp = 2-hydroxymethylpyridine) and NEt4MnO4 in MeCN gives NEt4[Mn-7(OH)(3)Cl-3(hmp)(9)]Cl[MnCl4] 1; the 4 Mn-II, 3 Mn-III cation comprises a Mn-6 hexagon containing a central Mn ion, and it possesses a S greater than or equal to 10 ground state.

引用

页码：1485 / 1486

页数：2