Polycyclic Imide Derivatives: Synthesis and Effective Tuning of Lowest Unoccupied Molecular Orbital Levels through Molecular Engineering

被引：56

作者：

Ding, Lin ^{[1
]}

Ying, Han-Ze ^{[1
]}

Zhou, Yan ^{[1
]}

Lei, Ting ^{[1
]}

Pei, Jian ^{[1
]}

机构：

[1] Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 23期

基金：

中国国家自然科学基金;

关键词：

FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; HIGH-PERFORMANCE; ELECTRON; SEMICONDUCTORS; DEPOSITION; STABILITY;

D O I：

10.1021/ol1024103

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of fluoranthene-fused imide derivatives were facilely developed through a Diels-Alder reaction followed by decarbonylation. The investigation of their photophysical and electrochemical properties demonstrated that their LUMO levels were effectively tuned from -3.2 to -3.8 eV through the introduction of a fused imide unit, which provides a platform to design new air-stable and solution-processable n-type materials.

引用

页码：5522 / 5525

页数：4

共 36 条

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